Publications

136. Nicholas A. Arnet, Sean F. McWilliams, Daniel E. DeRosha, Brandon Q. Mercado, Patrick L. Holland
Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron  
Inorg. Chem.  201756, 9185-9193.  
135. Masaki Horitani, Katarzyna Grubel, Sean F. McWilliams, Bryan D. Stubbert, Brandon Q. Mercado, Ying Yu, Prabhuodeyara M. Gurubasavaraj, Nicholas S. Lees, Patrick L. Holland, Brian M. Hoffman
ENDOR Characterization of an Iron-Alkene Complex Provides Insight into a Corresponding Organometallic Intermediate of Nitrogenase
Chem. Sci.  20178, 5941-5948.  
134. Sean F. McWilliams, Emma Brennan-Wydra, K. Cory MacLeod, Patrick L. Holland
Density Functional Calculations for Prediction of 57Fe Mössbauer Isomer Shifts and Quadrupole Splittings in β-Diketiminate Complexes
ACS Omega  20172, 2594-2606.  
133. Patrick L. Holland
Reaction: Opportunities for Sustainable Catalysts
Chem  20172, 443-444.  
132. Daniël L. J. Broere, Ilija Čorić, Anna Brosnahan, Patrick L. Holland
Quantitation of the THF Content in Fe[N(SiMe3)2]2·xTHF
Inorg. Chem.  201756, 3140–3143.  
131. Julian C. Lo, Dongyoung Kim, Chung-Mao Pan, Jacob T. Edwards, Yuki Yabe, Jinghan Gui, Tian Qin, Sara Gutiérrez, Jessica Giacoboni, Myles W. Smith, Patrick L. Holland, Phil S. Baran
Fe-Catalyzed C-C Bond Construction from Olefins via Radicals
J. Am. Chem. Soc.  2017139, 2484-2503.  
130. Daniel E. DeRosha, Brandon Q. Mercado, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Patrick L. Holland
Enhancement of C-H Oxidizing Ability in Co-O2 Complexes through an Isolated Heterobimetallic Oxo Intermediate
Angew. Chem. Int. Ed.  201756, 3211–3215.  
129. Megan E. Reesbeck, Katarzyna Grubel, Daniel Kim, William W. Brennessel, Brandon Q. Mercado, Patrick L. Holland
Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II)
Inorg. Chem.  201756, 1019-1022.  
128. K. Cory MacLeod, Richard A. Lewis, Daniel E. DeRosha, Brandon Q. Mercado, Patrick L. Holland
C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron
Angew. Chem. Int. Ed.  201756, 1069-1072.  
127. Amy M. Speelman, Patrick L. Holland
Sulfur-Supported Iron Complexes for Understanding N2 Reduction  
Topics in Organometallic Chemistry: Nitrogen Fixation  2017, in press.  
126. Gannon P. Connor, Patrick L. Holland
Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction
Catalysis Today  2017286, 21-40.  
125. Sarina M. Bellows, Nicholas A. Arnet, Prabhuodeyara M. Gurubasavaraj, William W. Brennessel, Eckhard Bill, Thomas R. Cundari, Patrick L. Holland
The Mechanism of N-N Double Bond Cleavage by an Iron(II)-Hydride Complex
J. Am. Chem. Soc.  2016138, 12112–12123.  
124. Yuchen Liu, David J. Vinyard, Megan E. Reesbeck, Tateki Suzuki, Kasidet Manakongtreecheep, Patrick L. Holland, Gary W. Brudvig, and Dieter Söll
A [3Fe-4S] cluster is required for tRNA thiolation in archaea and eukaryotes
Proc. Natl. Acad. Sci. USA  2016113, 12703-12708.  
123. K. Cory MacLeod, Fabian S. Menges, Sean F. McWilliams, Stephanie M. Craig, Brandon Q. Mercado, Mark A. Johnson, Patrick L. Holland
Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides
J. Am. Chem. Soc.  2016138, 11185-11191.  
122. K. Cory MacLeod, Sean F. McWilliams, Brandon Q. Mercado, Patrick L. Holland
Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia
Chem. Sci.  20167, 5736-5746.  
121. Ilija Čorić, Patrick L. Holland
Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands
J. Am. Chem. Soc.  2016138, 7200-7211.  
120. Sarina M. Bellows, William W. Brennessel, Patrick L. Holland
Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate β-Diketiminate Iron Complexes
Eur. J. Inorg. Chem.  2016, 3344-3355.  
119. Sean F. McWilliams, Kenton R. Rodgers, Gudrun Lukat-Rodgers, Brandon Q. Mercado, Katarzyna Grubel, Patrick L. Holland
Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes
Inorg. Chem.  201655, 2960-2968.  
118. Chi Chen, Maxwell Hecht, Aydin Kavara, William W. Brennessel, Brandon Q. Mercado, Daniel J. Weix, Patrick L. Holland
Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst
J. Am. Chem. Soc.  2015137, 13244-13247.  
117. Nicholas A. Arnet, Thomas R. Dugan, Fabian S. Menges, Brandon Q. Mercado, William W. Brennessel, Eckhard Bill, Mark A. Johnson, Patrick L. Holland
Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride
J. Am. Chem. Soc.  2015137, 13220-13223.  highlight in Nature Chemical Biology
116. Ilija Čorić, Brandon Q. Mercado, Eckhard Bill, David J. Vinyard, Patrick L. Holland
Binding of dinitrogen to an iron–sulfur–carbon site
Nature  2015526, 96-99.  
115. Malik H. Al-Afyouni, Elizaveta Suturina, Shubhrodeep Pathak, Mihail Atanasov, Eckhard Bill, Daniel E. DeRosha, William W. Brennessel, Frank Neese, Patrick L. Holland
Spin Isomers and Ligand Isomerization in a Three-Coordinate Cobalt(I) Carbonyl Complex
J. Am. Chem. Soc.  2015137, 10689-10699.  
114. Chi Chen, Sarina M. Bellows, Patrick L. Holland
Tuning steric and electronic effects in transition-metal β-diketiminate complexes
Dalton Trans.  201544, 16654-16670.  Open Access
113. Sean F. McWilliams, Patrick L. Holland
Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
Acc. Chem. Res.  201548, 2059–2065.  
112. Megan E. Reesbeck, Meghan M. Rodriguez, William W. Brennessel, Brandon Q. Mercado, David J. Vinyard, Patrick L. Holland
Oxidized and Reduced [2Fe-2S] Clusters from an Iron(I) Synthon
J. Biol. Inorg. Chem.  201520, 875-883.  
111. Patrick L. Holland
Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts
Acc. Chem. Res.  201548, 1696-1702.  
110. Simon J. Bonyhady, Jonathan M. Goldberg, Nicole Wedgwood, Thomas R. Dugan, Andrew G. Eklund, William W. Brennessel, Patrick L. Holland
Cobalt(II) Complex of a Diazoalkane Radical Anion
Inorg. Chem.  201554, 5148-5150.  
109. Amit Das, Zhiji Han, William W. Brennessel, Patrick L. Holland, Richard Eisenberg
Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water
ACS Catal.  20155, 1397-1406.  
108. Katarzyna Grubel, William W. Brennessel, Brandon Q. Mercado, Patrick L. Holland
Alkali Metal Control over N−N Cleavage in Iron Complexes
J. Am. Chem. Soc.  2014136, 16807-16816.  
107. Timothy E. Machonkin, Monica D. Boshart, Jeremy A. Schofield, Meghan M. Rodriguez, Katarzyna Grubel, Dalia Rokhsana, William W. Brennessel, Patrick L. Holland
Structural and Spectroscopic Characterization of Iron(II), Cobalt(II), and Nickel(II) ortho-Dihalophenolate Complexes: Insights into Metal–Halogen Secondary Bonding
Inorg. Chem.  201453, 9837-9848.  
106. Richard A. Lewis, K. Cory MacLeod, Brandon Q. Mercado, Patrick L. Holland
Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons
Chem. Commun.  201450 , 11114-11117.  
105. K. Cory MacLeod, David J. Vinyard, Patrick L. Holland
A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage
J. Am. Chem. Soc.  2014136, 10226-10229.  
104. John A. Gladysz, et al.
Organometallics Roundtable 2013-2014
Organometallics  201433, 1505-1527.  
103. Thomas R. Dugan, Eckhard Bill, K. Cory MacLeod, William W. Brennessel, Patrick L. Holland
Synthesis, Spectroscopy and Hydrogen/Deuterium Exchange in High-Spin Iron(II) Hydride Complexes
Inorg. Chem.  201453, 2370-2380.  
102. Chi Chen, Thomas R. Dugan, William W. Brennessel, Daniel J. Weix, Patrick L. Holland
Z-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes
J. Am. Chem. Soc.  2014136, 945-955.  Coverage in Org. Chem. Highlights
101. Karen P. Chiang, Sarina M. Bellows, William W. Brennessel, Patrick L. Holland
Multimetallic cooperativity in activation of dinitrogen at iron-potassium sites
Chem. Sci.  20145, 267-274.  
100. Wenwen Yao, Prabhuodeyara M. Gurubasavaraj, Patrick L. Holland
All-Ferrous Iron-Sulfur Clusters
Struct. Bonding  2014160, 1-37.  
99. Ryan E. Cowley, Matthew R. Golder, Nathan A. Eckert, Malik H. Al-Afyouni, Patrick L. Holland
Mechanism of Catalytic Nitrene Transfer using Iron(I)-Isocyanide Complexes
Organometallics  201332, 5289-5298.  
98. Zhiji Han, Luxi Shen, William W. Brennessel, Patrick L. Holland, Richard Eisenberg
Nickel Pyridylthiolate Complexes for the Photocatalytic Production of Hydrogen from Aqueous Solutions in Noble-Metal-Free Systems
J. Am. Chem. Soc.  2013135, 14659-14669.  
97. Sarina M. Bellows, Thomas R. Cundari, Patrick L. Holland
Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)- and Cobalt(II)-Alkyl Complexes
Organometallics   201332, 4741-4751.  Included in Virtual Issue Honoring Robert Bergman’s 2017 Wolf Prize in Chemistry
96. Christopher J. Pollock, Katarzyna Grubel, Patrick L. Holland, Serena DeBeer
Experimentally Quantifying Small Molecule Bond Activation Using Valence-to-Core X-ray Emission Spectroscopy
J. Am. Chem. Soc.  2013135, 11803-11808.  
95. Zuofeng Chen, Christopher R. K. Glasson, Patrick L. Holland, Thomas J. Meyer
Electrogenerated polypyridyl ruthenium hydride and ligand activation for water reduction to hydrogen and acetone to iso-propanol
Phys. Chem. Chem. Phys.  201315, 9503-9507.  
94. Roman M. Davydov, Matthew P. McLaughlin, Eckhard Bill, Brian M. Hoffman, Patrick L. Holland
Generation of High-Spin Iron(I) in a Protein Environment Using Cryoreduction
Inorg. Chem.  201352, 7323-7325.  
93. Thomas R. Dugan, K. Cory MacLeod, William W. Brennessel, Patrick L. Holland
Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges
Eur. J. Inorg. Chem.  2013, 3891-3897.  
92. Bryan D. Stubbert, Javier Vela, William W. Brennessel, Patrick L. Holland
A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4 Ligand
Z. Anorg. Allg. Chem.  2013639, 1351-1355.  
91. P. Chandrasekaran, Karen P. Chiang, Dennis Nordlund, Uwe Bergmann, Patrick L. Holland, Serena DeBeer
On the Sensitivity of X-ray Core Spectroscopy to Changes in Metal Ligation: A Systematic Study of Low-Coordinate High-Spin Ferrous Complexes
Inorg. Chem.  201352, 6286-6298.  
90. K. Cory MacLeod, Patrick L. Holland
Recent Developments in Homogeneous Dinitrogen Reduction by Molybdenum and Iron
Nature Chem.   20135, 559-565.  
89. Thomas R. Dugan, Eckhard Bill, K. Cory MacLeod, Gemma J. Christian, Ryan E. Cowley, William W. Brennessel, Shengfa Ye, Frank Neese, Patrick L. Holland
Reversible C-C Bond Formation Between Redox-Active Pyridine Ligands in Iron Complexes
J. Am. Chem. Soc.  2012134, 20352-20364.  
88. Matthew P. McLaughlin, Marius Retegan, Eckhard Bill, Thomas M. Payne, Hannah S. Shafaat, Salvador Peña, Jawahar Sudhamsu, Amy E. Ensign, Brian R. Crane, Frank Neese, Patrick L. Holland
Azurin as a protein scaffold for a low-coordinate non-heme iron site with a small-molecule binding pocket
J. Am. Chem. Soc.   2012134, 19746-19757.  
87. Brian L. Edelbach, Blaze M. Pharoah, Sarina M. Bellows, Peter R. Thayer, Charles N. Fennie, Ryan E. Cowley, Patrick L. Holland
An Expedient Synthesis of 2,4,6-Tris(trifluoromethyl)aniline
Synthesis  201244, 3595-3597.  
86. Zhiji Han, Fen Qiu, Richard Eisenberg, Patrick L. Holland, Todd D. Krauss
Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst
Science  2012338, 1321 1324.  
85. Christopher R. K. Glasson, Wenjing Song, Dennis L. Ashford, Aaron Vannucci, Zuofeng Chen, Javier J. Concepcion, Patrick L. Holland, Thomas J. Meyer
Self-Assembled Bilayers on Indium-Tin Oxide (SAB-ITO) Electrodes: A Design for Chromophore-Catalyst Photoanodes
Inorg. Chem.  201251, 8637-8639.  
84. Meghan M. Rodriguez, Bryan D. Stubbert, Christopher C. Scarborough, William W. Brennessel, Eckhard Bill, Patrick L. Holland
Isolation and Characterization of Stable Iron(I)-Sulfide Complexes
Angew. Chem. Int. Ed.   201251, 8246-8520.  
83. Ryan E. Cowley, Patrick L. Holland
Ligand Effects on Hydrogen Atom Transfer from Hydrocarbons to Three-Coordinate Iron Imides
Inorg. Chem.   201251, 8352-8361.  
82. Travis M. Figg, Patrick L. Holland, Thomas R. Cundari
Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation
Inorg. Chem.   201251, 7546-7550.  
81. William R. McNamara, Zhiji Han, Chih-Juo Yin, William W. Brennessel, Patrick L. Holland, Richard Eisenberg
Cobalt-Dithiolene Complexes for the Photocatalytic and Electrocatalytic Reduction of Protons in Aqueous Solutions
Proc. Natl. Acad. Sci. USA   2012109, 15594-15599.  
80. Karen P. Chiang, Christopher C. Scarborough, Masaki Horitani, Nicholas S. Lees, Keying Ding, Thomas R. Dugan, William W. Brennessel, Eckhard Bill, Brian M. Hoffman, Patrick L. Holland
Characterization of the Fe-H Bond in a Three-Coordinate Terminal Hydride Complex of Iron(I)
Angew. Chem. Int. Ed.  201251, 3658-3662.  
79. Katarzyna Grubel, Patrick L. Holland
New Iron-Sulfur Clusters Help Hydrogenases Tolerate Oxygen
Angew. Chem. Int. Ed.   201251, 3308-3310.  
78. Thomas R. Dugan, Jonathan M. Goldberg, William W. Brennessel, Patrick L. Holland
Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C-F Activation Reactions
Organometallics  201231, 1349-1360.  
77. Zhiji Han, William R. McNamara, Min-Sik Eum, Patrick L. Holland, Richard Eisenberg
A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System
Angew. Chem. Int. Ed.   201251, 1667-1670.  
76. Ryan E. Cowley, Gemma J. Christian, William W. Brennessel, Frank Neese, Patrick L. Holland
A Reduced β-Diketiminatoiron Complex with End-on and Side-on Nitriles: Strong Backbonding or Ligand Non-Innocence?
Eur. J. Inorg. Chem.   2012, 479-483.  
75. Barbara A. Reisner, Joanne L. Stewart, B. Scott Williams, Laurel A. Goj, Patrick L. Holland, Hilary J. Eppley, and Adam R. Johnson
Virtual Inorganic Pedagogical Electronic Resource Learning Objects in Organometallic Chemistry
J. Chem. Educ.   201289, 185-187.  
74. Meghan M. Rodriguez, Eckhard Bill, William W. Brennessel, Patrick L. Holland
N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex
Science  2011334, 780-783.  Reprint
73. Matthew P. McLaughlin, Thomas H. Darrah, Patrick L. Holland
Palladium(II) and platinum(II) bind strongly to an engineered blue copper protein
Inorg. Chem.   201150, 11294-11296.  
72. Mario U. Delgado-Jaime, Benjamin R. Dible, Karen P. Chiang, William W. Brennessel, Patrick L. Holland, Uwe Bergmann, Serena DeBeer
Identification of Light Atoms within Multinuclear Metal Clusters using Valence-to-Core X-Ray Emission Spectroscopy  
Inorg. Chem.  201150, 10709-10717.  
71. Theresa M. McCormick, Zhiji Han, David J. Weinberg, Patrick L. Holland, Richard Eisenberg
The Impact of Ligand Exchange in Hydrogen Production from Cobaloxime-Containing Photocatalytic Systems
Inorg. Chem.  201150, 10660-10666.  
70. William R. McNamara, Zhiji Han, Paul J. Alperin, William W. Brennessel, Patrick L. Holland, Richard Eisenberg
Cobalt-Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons
J. Am. Chem. Soc.  2011133, 5123-5132.  
69. Benjamin R. Dible, Ryan E. Cowley, Patrick L. Holland
Remote Substitution on N-Heterocyclic Carbenes Heightens the Catalytic Reactivity of Their Palladium Complexes
Organometallics   201130, 5123-5132.  
68. Thomas R. Dugan, Xianru Sun, Elena V. Rybak-Akimova, Olayinka Olatunji-Ojo, Thomas R. Cundari, Patrick L. Holland
A Masked Two-Coordinate Cobalt(I) Complex That Activates C-F Bonds
J. Am. Chem. Soc.   2011133, 12418-12421.  
67. Patrick L. Holland
Techniques Used in Functional and Structural Modeling of Nitrogenase
Methods in Molecular Biology - Nitrogen Fixation   2011(M. Ribbe, ed.), Springer: New York, 249-263.  
66. Matthew P. McLaughlin, Theresa M. McCormick, Richard Eisenberg, Patrick L. Holland
A stable molecular nickel catalyst for the homogeneous photogeneration of hydrogen in aqueous solution
Chem. Commun.   201147, 7989-7981.  
65. Ryan E. Cowley, Nathan A. Eckert, Sridhar Vaddadi, Travis M. Figg, Thomas R. Cundari, Patrick L. Holland
Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex
J. Am. Chem. Soc.   2011133, 9796-9811.  
64. Patrick L. Holland
All square with high-spin iron(II)
Nature Chem.  20113, 507-508.  
63. Patrick L. Holland
Two-Coordinate Transition Metal Centers With Metal-Metal Bonds
Angew. Chem. Int. Ed.  201150, 6213-6214.  
62. Ryan E. Cowley, Patrick L. Holland
C-H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product
Inorg. Chim. Acta   2011369, 40-44.  
61. Sara S. Rocks, William W. Brennessel, Timothy E. Machonkin, Patrick L. Holland
Solution and Structural Characterization of Iron(II) Complexes with Ortho-Halogenated Phenolates: Insights into Potential Substrate Binding Modes in Hydroquinone Dioxygenases
Inorg. Chem.   201049, 10914-10929.  
60. Ryan E. Cowley, Nathan J. DeYonker, Nathan A. Eckert, Thomas R. Cundari, Serena DeBeer, Eckhard Bill, Xavier Ottenwaelder, Christine Flaschenriem, Patrick L. Holland
Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation
Inorg. Chem.  201049, 6172-6187.  
59. Daniel J. Mindiola, Patrick L. Holland, Timothy H. Warren
Complexes of Bulky Beta-Diketiminate Ligands: Introduction
Inorg. Synth.  201035, 1-4.  
58. Matthew S. Varonka, Timothy H. Warren, Thomas R. Dugan, Ryan E. Cowley, Patrick L. Holland
Beta-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3
Inorg. Synth.  201035, 4-8.  
57. Debashis Adhikari, Ba L. Tran, Francisco J. Zuno-Cruz, Gloria Sanchez Cabrera, Daniel J. Mindiola, Karen P. Chiang, Ryan E. Cowley, Thomas R. Dugan, Patrick L. Holland
Beta-Diketiminate Precursors LMe,iPr2H, [LMe,iPr2Li]x, and [LtBu,iPr2K]x
Inorg. Synth.  201035, 8-13.  
56. Ryan E. Cowley, Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Francisco J. Zuno-Cruz, Gloria Sanchez Cabrera, Daniel J. Mindiola
Beta-Diketiminate Precursors LtBu,iPr2H and LtBu,iPr2Li(THF)
Inorg. Synth.  201035, 13-19.  
55. Bryan D. Stubbert, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola
Iron 2,4-Bis-(2,6-diisopropylphenylimido)pentyl Chloride Dimer
Inorg. Synth.  201035, 38-41.  
54. Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola
Iron 2,2,6-6-Tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl Chloride
Inorg. Synth.  201035, 41-43.  
53. Keying Ding, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola
Cobalt 2,2,6-6-Tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl Chloride
Inorg. Synth.  201035, 43-45.  
52. Marie M. Melzer, Elzbieta Kogut, Matthew S. Varonka, Stefan Wiese, Timothy H. Warren, Sara S. Rocks, Patrick L. Holland
Beta-Diketiminate Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3
Inorg. Synth.  201035, 45-48.  
51. Thomas R. Dugan, Patrick L. Holland, Stefan Wiese, Timothy H. Warren
Nickel 2,4-Bis-(2,6-diisopropylphenylimido)pentyl Chloride Dimer
Inorg. Synth.  201035, 48-50.  
50. Yosra M. Badiei, Timothy H. Warren, Karen P. Chiang, Patrick L. Holland
Bis[Copper 2,4-Bis-(2,4,6-trimethylphenylimido)pentyl] Toluene
Inorg. Synth.  201035, 50-53.  
49. Patrick L. Holland, Marie M. Melzer, Timothy H. Warren
Copper 2,4-Bis-(2,6-diisopropylphenylimido)pentyl Chloride
Inorg. Synth.  201035, 54-55.  
48. Patrick L. Holland
Metal-Dioxygen and Metal-Dinitrogen Complexes: Where Are The Electrons?
Dalton Trans.  201039, 5415-5425.  
47. Timothy E. Machonkin, Patrick L. Holland, Kristine N. Smith, Justin S. Liberman, Adriana Dinescu, Thomas R. Cundari, Sara S. Rocks
Determination of the Active Site of Sphingomonas chlorophenolica 2,6-dichloro-p-hydroquinone dioxygenase (PcpA)
J. Biol. Inorg. Chem.   201015, 291-301.  
46. Keying Ding, Thomas R. Dugan, William W. Brennessel, Eckhard Bill, and Patrick L. Holland
Synthesis, Properties, and Reactivity of Diketiminate-Supported Cobalt Fluoride Complexes
Organometallics  200928, 6650-6656.  
45. Keying Ding, Ferdous Zannat, James C. Morris, William W. Brennessel, and Patrick L. Holland
Coordination of N-Methylpyrrolidone to Iron(II)
J. Organomet. Chem.   2009694, 4204-4208.  
44. Keying Ding, William W. Brennessel, and Patrick L. Holland
Three-Coordinate and Four-Coordinate Cobalt Hydride Complexes That React with Dinitrogen
J. Am. Chem. Soc.  2009131, 10804-10805.  Correction
43. Keying Ding, Aaron W. Pierpont, William W. Brennessel, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Thomas R. Cundari, Eckhard Bill and Patrick L. Holland
Cobalt-Dinitrogen Complexes with Weakened N-N Bonds
J. Am. Chem. Soc.   2009131, 9471-9472.  
42. Thomas R. Dugan, Patrick L. Holland
New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H2
J. Organomet. Chem.   2009694, 2825-2830.  
41. Karen P. Chiang, Pamela M. Barrett, Feizhi Ding, Jeremy M. Smith, Savariraj Kingsley, William W. Brennessel, Meghan M. Clark, Rene J. Lachicotte, Patrick L. Holland
Ligand Dependence of Binding to Three-Coordinate Fe(II) Complexes
Inorg. Chem.  200948, 5106-5116.  
40. Ryan E. Cowley, Eckhard Bill, Frank Neese, William W. Brennessel, Patrick L. Holland
Iron(II) Complexes With Redox-Active Tetrazene (RNNNNR) Ligands
Inorg. Chem.  200948, 4828-4836.  
39. Azwana R. Sadique, William W. Brennessel, Patrick L. Holland
A diketiminate-bound diiron complex with a bridging carbonate ligand
Acta Cryst. C  200965, m174-m176.  
38. Meghan M. Clark, William W. Brennessel, Patrick L. Holland
Bis(η5-pentamethylcyclopentadienyl)cobalt(II)
Acta Cryst. C   200965, m391.  More on Decamethylcobaltocene
37. Ryan E. Cowley, Nathan A. Eckert, Jerome E. Elhaïk, Patrick L. Holland
Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates
Chem. Commun.   2009, 1760-1762.  
36. Patrick L. Holland
Nitrogen Fixation
McGraw-Hill Yearbook of Science & Technology  2009, 255-256.  
35. Sara S. Rocks, William W. Brennessel, Timothy E. Machonkin, Patrick L. Holland
Solid-State and Proton NMR Characterization of an Iron(II) Complex of a Tridentate, Facially Coordinating N,N,O Donor Ligand
Inorg. Chim. Acta   2009362, 1387-1390.  
34. Sebastian Stoian, Jeremy M. Smith, Patrick L. Holland, Eckard Münck, Emile L. Bominaar
Mössbauer, EPR, and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complex
Inorg. Chem.  200847, 8687-8695.  
33. Patrick L. Holland
Electronic Structure and Reactivity of Three-Coordinate Iron Complexes
Acc. Chem. Res.  200841, 905-914.  
32. Ying Yu, Azwana R. Sadique, Jeremy M. Smith, Thomas R. Dugan, Ryan E. Cowley, William W. Brennessel, Christine J. Flaschenriem, Eckhard Bill, Thomas R. Cundari, Patrick L. Holland
The Reactivity Patterns of Low-Coordinate Iron Hydride Complexes
J. Am. Chem. Soc.   2008130, 6624-6638.  
31. Ryan E. Cowley, Jerome Elhaik, Nathan A. Eckert, William W. Brennessel, Eckhard Bill, Patrick L. Holland
A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides
J. Am. Chem. Soc.  2008130, 6074-6075.  Highlight in Chemical & Engineering News
30. Azwana R. Sadique, William W. Brennessel, and Patrick L. Holland
Reduction of COto CO Using Low-Coordinate Iron: Formation of a Four-Coordinate Iron Dicarbonyl Complex and a Bridging Carbonate Complex
Inorg. Chem.   200847, 784-786.  
29. Nicholas S. Lees, Rebecca L. McNaughton, Wilda Vargas Gregory, Patrick L. Holland, and Brian M. Hoffman
ENDOR Characterization of a Synthetic Diiron Hydrazido Complex as a Model for Nitrogenase Intermediates
J. Am. Chem. Soc.   2008130, 546-555.  
28. Azwana R. Sadique, Elizabeth A. Gregory, William W. Brennessel, and Patrick L. Holland
Mechanistic Insight into N=N Cleavage by a Low-Coordinate Iron(II) Hydride Complex
J. Am. Chem. Soc.   2007129, 8112-8121.  Editor's Choice in Science
27. Javier Vela, Liwei Zhu, Christine J. Flaschenriem, William W. Brennessel, Rene J. Lachicotte, and Patrick L. Holland
Macrocyclic Binucleating β-Diketiminate Ligands and their Lithium, Aluminum, and Zinc Complexes
Organometallics  200726, 3416-3423.  
26. Ying Yu, William W. Brennessel, and Patrick L. Holland
Borane B-C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N-N Bond Cleavage by the Hydridoborate Product
Organometallics  200726, 3217-3226.  
25. Javier Vela, Jordi Cirera, Jeremy M. Smith, Rene J. Lachicotte, Christine J. Flaschenriem, Santiago Alvarez, and Patrick L. Holland
Quantitative Geometric Descriptions of the Belt Iron Atoms of the Iron-Molybdenum Cofactor of Nitrogenase and Synthetic Iron(II) Model Complexes
Inorg. Chem.  200746, 60-71.  
24. Nathan A. Eckert, Sridhar Vaddadi, Sebastian Stoian, Rene J. Lachicotte, Thomas R. Cundari, and Patrick L. Holland
Coordination Number Dependence of Reactivity in an Imidoiron(III) Complex
Angew. Chem., Int. Ed. Engl.   200645, 6868-6871.  
23. Travis J. Hebden, William W. Brennessel, Christine J. Flaschenriem, and Patrick L. Holland
A dinucleating ligand related to the β-diketiminates
Dalton Trans.   2006, 3855-3857.  
22. Sebastian A. Stoian, Javier Vela, Jeremy M. Smith, Azwana R. Sadique, Patrick L. Holland, Eckard Münck, and Emile L. Bominaar
Mössbauer and Computational Study of an N2-Bridged Diiron Diketiminate Complex: Parallel Alignment of the Iron Spins by Direct Antiferromagnetic Exchange with Activated Dinitrogen
J. Am. Chem. Soc.   2006128, 10181-10192.  
21. Ying Yu, Jeremy M. Smith, Christine J. Flaschenriem, and Patrick L. Holland
Binding Affinity of Alkynes and Alkenes to Low-Coordinate Iron
Inorg. Chem.  200645, 5742-5751.  cover of Inorg. Chem.
20. Javier Vela, Sridhar Vaddadi, Savariraj Kingsley, Christine J. Flaschenriem, Rene J. Lachicotte, Thomas R. Cundari, Patrick L. Holland
Bidentate Coordination of Pyrazolate in Low-Coordinate Iron(II) and Nickel(II) Complexes
Angew. Chem., Int. Ed. Engl.   200645, 1607-1611.  
19. Jeremy M. Smith, Azwana R. Sadique, Thomas R. Cundari, Kenton R. Rodgers, Gudrun Lukat-Rodgers, Rene J. Lachicotte, Christine J. Flaschenriem, Javier Vela, and Patrick L. Holland
Studies of Low-Coordinate Iron Dinitrogen Complexes
J. Am. Chem. Soc.   2006128, 756-769.  
18. Nathan A. Eckert, Adriana Dinescu, Thomas R. Cundari, Patrick L. Holland
A T-Shaped Three-Coordinate Nickel(I) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes
Inorg. Chem.  200544, 7702-7704.  
17. Nathan A. Eckert, Sebastian Stoian, Jeremy M. Smith, Emile L. Bominaar, Eckard Münck, Patrick L. Holland
Synthesis, Structure, and Spectroscopy of an Oxodiiron(II) Complex
J. Am. Chem. Soc.   2005127, 9344-9345.  
16. Sebastian Stoian, Ying Yu, Jeremy M. Smith, Patrick L. Holland, Emile L. Bominaar, Eckard Münck
Mössbauer, EPR and Crystallographic Characterization of a High-Spin Fe(I) Diketiminate Complex with Orbital Degeneracy
Inorg. Chem.   200544, 4915-4922.  
15. Javier Vela, Jeremy M. Smith, Ying Yu, Nicole A. Ketterer, Christine J. Flaschenriem, Rene J. Lachicotte, Patrick L. Holland
Synthesis and Reactivity of Low-Coordinate Iron(II) Fluoride Complexes and Their Use in the Catalytic Hydrodefluorination of Fluorocarbons
J. Am. Chem. Soc.   2005127, 7857-7870.  
14. Elizabeth A. Gregory, Rene J. Lachicotte, Patrick L. Holland
A Cationic Three-Coordinate Iron(II) Complex and the Reaction of Diketiminate with Ethyl Diazoacetate
Organometallics  200524, 1803-1805.  
13. Patrick L. Holland
Low-Coordinate Iron Complexes as Synthetic Models of Nitrogenase
Can. J. Chem.   200583, 296-301.  
12. Javier Vela, Sridhar Vaddadi, Thomas R. Cundari, Jeremy M. Smith, Elizabeth A. Gregory, Rene J. Lachicotte, Christine J. Flaschenriem, Patrick L. Holland
Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies
Organometallics   200423, 5226-5239.  Correction
11. Nathan A. Eckert, Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland
Low-coordinate Fe(II) Amido Complexes of β-Diketiminates: Synthesis, Structure and Reactivity
Inorg. Chem.  200443, 3306-3321.  
10. Javier Vela, Sebastian Stoian, Christine Flaschenriem, Eckard Münck, Patrick L. Holland
A Sulfido-Bridged Diiron(II) Compound and Its Reactions with Nitrogenase-Relevant Substrates
J. Am. Chem. Soc.   2004126, 4522-4523.  Correction
9. Patrick L. Holland
“Nitrogen Fixation,” In Comprehensive Coordination Chemistry 2 (McCleverty, J., Meyer, T. J., Eds.)
  2004Vol. 8; Elsevier: Oxford, 569-599.  On-line access
8. Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland
N=N Bond Cleavage by a Low-Coordinate Iron(II) Hydride Complex
J. Am. Chem. Soc.   2003125, 15752-15753.  
7. Nathan A. Eckert, Emily M. Bones, Rene J. Lachicotte, Patrick L. Holland
Nickel Complexes of a Bulky β-Diketiminate Ligand
Inorg. Chem.  200342, 1720-1725.  
6. Javier Vela, Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland
Alkyl group isomerisation in three-coordinate iron(II) complexes
Chem. Commun.   2002, 2886-2887.  
5. Patrick L. Holland, Thomas R. Cundari, Lanyn L. Perez, Nathan A. Eckert, Rene J. Lachicotte
Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel
J. Am. Chem. Soc.   2002124, 14416-14424.  
4. Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland
Three-coordinate, 12-electron organometallic complexes of iron(II): synthesis and insertion of CO to give square pyramidal complexes
Organometallics   200221, 4808-4814.  
3. Hanspeter Andres, Emile M. Bominaar, Jeremy M. Smith, Nathan A. Eckert, Patrick L. Holland, Eckard Münck
Planar Three-Coordinate High-Spin Fe(II) Complexes with Large Orbital Angular Momentum: Mössbauer, Electron Paramagnetic Resonance, and Electronic Structure Studies
J. Am. Chem. Soc.   2002124, 3012-3025.  Correction
2. Jeremy M. Smith, Rene J. Lachicotte, Karl A. Pittard, Thomas R. Cundari, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Patrick L. Holland
Stepwise Reduction of N-N Bond Order by a Low-Coordinate Iron Complex
J. Am. Chem. Soc.   2001123, 9222-9223.  
1. Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland
Tuning Metal Coordination Number by Ancillary Ligand Steric Effects: Synthesis of a Three-Coordinate Iron(II) Complex
Chem. Commun.   2001, 1542-1543.