Publications

198.	Sarah R. Buzsaki, Savannah M. Mason, Padmanabha V. Kattamuri, Juan M. I. Serviano, Dinora N. Rodriguez, Conner V. Wilson, Drew M. Hood, Jonathan D. Ellefsen, Yen-Chu Lu, Jolie Kan, Julian G. West, Scott J. Miller, Patrick L. Holland Fe/Thiol Cooperative HAT Olefin Hydrogenation: Mechanistic Insights that Inform Enantioselective Catalysis submitted , , . ChemRxiv
197.	Reagan X. Hooper, Ashlee E. Wertz, Hannah S. Shafaat, Patrick L. Holland Evaluating Diazene to N₂ Interconversion at Iron-Sulfur Complexes Chem. Eur. J. 2024, 30, in press.
196.	Alexandra L. Nagelski, Mykhaylo Ozerov, Majed S. Fataftah, J. Krzystek, Samuel M. Greer, Patrick L. Holland, Joshua Telser Electronic Structure of Three-Coordinate Fe^II and Co^II β-Diketiminate Complexes Inorg. Chem. 2024, 63, in press.
195.	Tong-De Tan, Juan M. I. Serviano, Xiaohua Luo, Peng-Cheng Qian, Patrick L. Holland, Xinglong Zhang, Ming Joo Koh Congested C(sp³)-rich architectures enabled by iron-catalysed conjunctive alkylation Nature Catal. 2024, 7, in press.
194.	Daniel W. N. Wilson, Majed S. Fataftah, Zachary Mathe, Brandon Q. Mercado, Serena DeBeer, Patrick L. Holland Three-Coordinate Nickel and Metal-Metal Interactions in a Heterometallic Iron-Sulfur Cluster J. Am. Chem. Soc. 2024, 146, 4013–4025. ChemRxiv
193.	Samuel M. Bhutto, Reagan X. Hooper, Sean F. McWilliams, Brandon Q. Mercado, Patrick L. Holland Iron(IV) alkyl complexes: electronic structure contributions to Fe–C bond homolysis and migration reactions that form N–C bonds from N₂ Chem. Sci. 2024, 15, 3485-3494. Highlight in OPR&D
192.	Conner V. Wilson, Patrick L. Holland Mechanism of Alkene Hydrofunctionalization by Oxidative Cobalt(salen) Catalyzed Hydrogen Atom Transfer J. Am. Chem. Soc. 2024, 146, 2685–2700.
191.	Aleksandra Wandzilak, Katarzyna Grubel, Kazimer L. Skubi, Sean F. McWilliams, Dimitrios Bessas, Atanu Rana, Stefan Hugenbruch, Abhishek Dey, Patrick L. Holland, Serena DeBeer Mössbauer and Nuclear Resonance Vibrational Spectroscopy Studies of Iron Species Involved in N–N Bond Cleavage Inorg. Chem. 2023, 62, 18449–18464.
190.	Alexandre Genoux, Magnus Pauly, Conor L. Rooney, Chungseok Choi, Bo Shang, Scott McGuigan, Majed S. Fataftah, Yves Kayser, Simon C. B. Suhr, Serena DeBeer, Hailiang Wang, Paul A. Maggard, Patrick L. Holland Well-Defined Iron Sites in Crystalline Carbon Nitride J. Am. Chem. Soc. 2023, 145, 20739–20744.
189.	Majed S. Fataftah, Brandon Q. Mercado, Patrick L. Holland Valence delocalization in carbon-bridged mixed-valence iron complexes Chem. Eur. J. 2023, 29, e202301962.
188.	Reagan X. Hooper, Brandon Q. Mercado, Patrick L. Holland Desulfurization and N₂ Binding at an Iron Complex Derived from C−S Activation of Benzothiophene Organometallics 2023, 42, 2019-2027.
187.	Samuel M. Bhutto, Brandon Q. Mercado, Patrick L. Holland Dinitrogen Binding and Functionalization from a Low-Coordinate Alkynyliron Complex Inorg. Chem. 2023, 62, 9335-9342.
186.	Alexandre T.-Y. Genoux, Stephen J. Tereniak, Patrick L. Holland Synthesis of new chelating phosphines containing an aryl chloride group Synthesis 2023, 55, 2737-2741.
185.	Juan M. I. Serviano, Erik J. T. Phipps, Patrick L. Holland Intermolecular Hydroalkoxylation and Hydrocarboxylation of 2-Azadienes with High Efficiency J. Org. Chem. 2023, 88, 3277-3281.
184.	Faraj Hasanayn, Patrick L. Holland, Alan S. Goldman, Alexander J. M. Miller Lewis Structures and the Bonding Classification of End-on Bridging Dinitrogen Transition Metal Complexes J. Am. Chem. Soc. 2023, 145, 4326-4342.
183.	Samuel M. Bhutto, Reagan X. Hooper, Brandon Q. Mercado, Patrick L. Holland Mechanism of Nitrogen-Carbon Bond Formation From Iron(IV) Disilylhydrazido Intermediates During N₂ Reduction J. Am. Chem. Soc. 2023, 145, 4626-4637.
182.	Sean F. McWilliams, Brandon Q. Mercado, K. Cory MacLeod, Majed S. Fataftah, Maxime Tarrago, Xiaoping Wang, Eckhard Bill, Shengfa Ye, Patrick L. Holland Dynamic Effects on Ligand Field from Rapid Hydride Motion in an Iron(II) Dimer with an S=3 Ground State Chem. Sci. 2023, 14, 2303-2312. ORNL press release
181.	Sivathmeehan Yogendra, Daniel W. Wilson, Anselm Hahn, Thomas Weyhermüller, Casey Van Stappen, Patrick L. Holland, Serena DeBeer Sulfur-Ligated [2Fe-2C] Clusters as Synthetic Model Systems for Nitrogenase Inorg. Chem. 2023, 62, 2663-2671.
180.	Alexander S. Hegg, Brandon Q. Mercado, Alexander J. M. Miller, Patrick L. Holland Catalytic Reduction of Dinitrogen to Ammonia using Molybdenum Porphyrin Complexes Faraday Disc. 2023, 243, 429-449.
179.	Conner V. Wilson, Dongyoung Kim, Ajay Sharma, Reagan X. Hooper, Rinaldo Poli, Brian M. Hoffman, Patrick L. Holland Cobalt-Carbon Bonding in a Salen-Supported Cobalt(IV) Alkyl Complex Postulated in Oxidative MHAT Catalysis J. Am. Chem. Soc. 2022, 144, 10361-10367.
178.	Gannon P. Connor, Daniel Delony, Jeremy E. Weber, Brandon Q. Mercado, Julia B. Curley, Sven Schneider, James M. Mayer, Patrick L. Holland Facile conversion of ammonia to a nitride in a rhenium system that cleaves dinitrogen Chem. Sci. 2022, 13, 4010-4018.
177.	Kazimer L. Skubi, Reagan X. Hooper, Brandon Q. Mercado, Melissa M. Bollmeyer, Samantha N. MacMillan, Kyle M. Lancaster, Patrick L. Holland Iron Complexes of a Proton-Responsive SCS Pincer Ligand with a Sensitive Electronic Structure Inorg. Chem. 2022, 61, 1644-1658.
176.	Patrick L. Holland Introduction: Volume I Comprehensive Organometallic Chemistry IV 2022, Vol. 1, 1.
175.	Jeremy E. Weber, Samuel M. Bhutto, Alexandre T.-Y. Genoux, Patrick L. Holland Dinitrogen Binding and Functionalization Comprehensive Organometallic Chemistry IV 2022, Vol. 1, 521-554.
174.	Daniel W. N. Wilson, Patrick L. Holland Nitrogenases and model complexes in bioorganometallic chemistry Comprehensive Organometallic Chemistry IV 2022, Vol. 15, 41-72.
174.	Daniel Kim, Daniel W. N. Wilson, Majed S. Fataftah, Brandon Q. Mercado and Patrick L. Holland Spin states, bonding and magnetism in mixed valence iron(0)–iron(II) complexes Chem. Eur. J. 2022, 28, e202104431.
173.	Lynn S. Yamout, Mohamad Ataya, Faraj Hasanayn, Patrick L. Holland, Alexander J. M. Miller, Alan S. Goldman Understanding Terminal versus Bridging End-on N₂ Coordination in Transition Metal Complexes J. Am. Chem. Soc. 2021, 143, 9744–9757.
171.	Jeremy E. Weber, Faraj Hasanayn, Majed S. Fataftah, Brandon Q. Mercado, Robert H. Crabtree, Patrick L. Holland Electronic and Spin-State Effects on Dinitrogen Splitting to Nitrides in a Rhenium Pincer System Inorg. Chem. 2021, 60, 6115-6124.
170.	Daniel J. DiPrimio, Patrick L. Holland Repurposing Metalloproteins as Mimics of Natural Metalloenzymes for Small-Molecule Activation J. Inorg. Biochem. 2021, 219, 111430.
169.	John W. Peters, Oliver Einsle, Dennis R. Dean, Serena DeBeer, Brian M. Hoffman, Patrick L. Holland, Lance C. Seefeldt Comment on “Structural evidence for a dynamic metallocofactor during N₂ reduction by Mo-nitrogenase” Science 2021, 371, eabe5481.
168.	Daniel Kim, Guy Pillon, Daniel J. DiPrimio, Patrick L. Holland Highly Z-Selective Double Bond Transposition in Simple Alkenes and Allylarenes Through A Spin-Accelerated Allyl Mechanism J. Am. Chem. Soc. 2021, 143, 3070–3074.
167.	Amy L. Speelman, Kazimer L. Skubi, Brandon Q. Mercado, Patrick L. Holland Synthesis and Reactivity of Iron Complexes with a Biomimetic SCS Pincer Ligand Inorg. Chem. 2021, 60, 1965-1974.
166.	Sophia L. Shevick, Conner V. Wilson, Simona Kotesova, Dongyoung Kim, Patrick L. Holland, and Ryan Shenvi Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals Chem. Sci. 2020, 11, 12386-12400. Tenth anniversary issue
165.	Quinton J. Bruch, Gannon P. Connor, Noah D. McMillion, Alan S. Goldman, Faraj Hasanayn, Patrick L. Holland, Alexander J. M. Miller Considering Electrocatalytic Ammonia Synthesis via Bimetallic Dinitrogen Cleavage ACS Catal. 2020, 10, 10826–10846.
164.	Alexandra L. Nagelski, Majed S. Fataftah, Melissa M. Bollmeyer, Sean F. McWilliams, Samantha N. MacMillan, Brandon Q. Mercado, Kyle M. Lancaster, Patrick L. Holland The Influences of Carbon Donor Ligands on Biomimetic Multi-Iron Complexes for N₂ Reduction Chem. Sci. 2020, 11, 12710-12720. Tenth anniversary issue
163.	Sean F. McWilliams, Daniel L. J. Broere, Connor J. V. Halliday, Samuel M. Bhutto, Brandon Q. Mercado, Patrick L. Holland Coupling Dinitrogen and Hydrocarbons through Aryl Migration Nature 2020, 584, 221-226. Chem. Eng. News "Research of the Year"
162.	Daniel Kim, Chi Chen, Brandon Q. Mercado, Daniel J. Weix, Patrick L. Holland Mechanistic Study of Alkene Hydrosilylation Catalyzed by a β-Dialdiminate Cobalt(I) Complex Organometallics 2020, 39, 2415-2424.
161.	Patrick L. Holland Introduction: Reactivity of Nitrogen from the Ground to the Atmosphere Chem. Rev. 2020, 120, 4919-4920. Guest Editor for Thematic Issue of Chemical Reviews
160.	Gal Hochman, Alan S. Goldman, Frank A. Felder, James M. Mayer, Alexander J. M. Miller, Patrick L. Holland, Leo A. Goldman, Patricia Manocha, Ze Song, Saketh Aleti The Potential Economic Feasibility of Direct Electrochemical Nitrogen Reduction as a Route to Ammonia ACS Sustainable Chem. Eng. 2020, 8, 8938-8948.
159.	Quinton J. Bruch, Gannon P. Connor, Chun-Hsing Chen, Patrick L. Holland, James M. Mayer, Faraj Hasanayn, Alexander J. M. Miller Dinitrogen Reduction to Ammonium at Rhenium Utilizing Light and Proton-Coupled Electron Transfer J. Am. Chem. Soc. 2019, 141, 20198-20208. (Spotlight)
158.	K. Cory MacLeod, Ida M. DiMucci, Edward P. Zovinka, Sean F. McWilliams, Brandon Q. Mercado, Kyle M. Lancaster, Patrick L. Holland Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene Organometallics 2019, 38, 4224-4232.
157.	Amy L. Speelman, Ilija Čorić, Casey Van Stappen, Serena DeBeer, Brandon Q. Mercado, Patrick L. Holland Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site J. Am. Chem. Soc. 2019, 141, 13148-13157.
156.	Gannon P. Connor, Brandon Q. Mercado, Hannah M. C. Lant, James M. Mayer, Patrick L. Holland Chemical oxidation of a coordinated PNP-pincer ligand forms unexpected Re-nitroxide complexes with reversal of nitride reactivity Inorg. Chem. 2019, 58, 10791-10801.
155.	Gannon P. Connor, Daniel Kim, Alexandra L. Nagelski, Emily O. Schmidt, Tori Hass-Mitchell, John T. Atwater, Sara A. Tridenti, Seungjung Sohn, Patrick L. Holland Implementation of an Accessible Gas Chromatography Laboratory Experiment for High School Students J. Chem. Ed. 2019, 96, 1707-1713. (links to extra supporting materials)
154.	Daniel E. DeRosha, Vijay G. Chilkuri, Casey Van Stappen, Eckhard Bill, Brandon Q. Mercado, Serena DeBeer, Frank Neese, Patrick L. Holland Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity Nature Chem. 2019, 11, 1019-1025.
153.	Daniel E. DeRosha, Nicholas A. Arnet, Brandon Q. Mercado, and Patrick L. Holland A [2Fe-1S] Complex that Affords Access to Bimetallic and Higher Nuclearity Iron-Sulfur Clusters Inorg. Chem. 2019, 58, 8829-8834.
152.	Dongyoung Kim, S. M. Wahidur Rahaman, Brandon Q. Mercado, Rinaldo Poli, Patrick L. Holland Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study J. Am. Chem. Soc. 2019, 141, 7473-7485. (Highlight in Science)
151.	Samuel M. Bhutto, Patrick L. Holland Dinitrogen Activation and Functionalization Using Beta-Diketiminate Iron Complexes Eur. J. Inorg. Chem. 2019, , 1861-1869.
150.	Lisa Roy, Malik H. Al-Afyouni, Daniel E. DeRosha, Bhaskar Mondal, Ida M. DiMucci, Kyle M. Lancaster, Jason Shearer, Eckhard Bill, William W. Brennessel, Frank Neese, Shengfa Ye, Patrick L. Holland Reduction of CO₂ by a Masked Two-Coordinate Cobalt(I) Complex and Characterization of a Proposed Oxodicobalt(II) Intermediate Chem. Sci. 2019, 10, 918-929.
149.	Sean F. McWilliams, Philip C. Bunting, Venkatesan Kathiresan, Brandon Q. Mercado, Brian M. Hoffman, Jeffrey R. Long, Patrick L. Holland Isolation and Characterization of a High-Spin Mixed-Valent Iron Dinitrogen Complex Chem. Commun. 2018, 54, 13339-13342.
148.	Sean F. McWilliams, Eckhard Bill, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Brandon Q. Mercado, Patrick L. Holland Effects of N₂Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex J. Am. Chem. Soc. 2018, 140, 8586–8598.
147.	Kazimer L. Skubi, Patrick L. Holland So Close, Yet Sulfur Away: Opening the Nitrogenase Cofactor Structure Creates a Binding Site Biochemistry 2018, 57, 3540-3541.
146.	Vladimir Pelmenschikov, Leland B. Gee, Hongxin Wang, K. Cory MacLeod, Sean F. McWilliams, Kazimer L. Skubi, Stephen P. Cramer, Patrick L. Holland High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT Angew. Chem. Int. Ed. 2018, 57, 9367-9371.
145.	J. G. Chen, R. M. Crooks, L. C. Seefeldt, K. L. Bren, R. M. Bullock, M. Y. Darensbourg, P. L. Holland, M. J. Janik, A. K. Jones, M. G. Kanatzidis, P. King, K. M. Lancaster, S. V. Lymar, P. Pfromm, W. F. Schneider, R. R. Schrock Beyond fossil-fuel-driven nitrogen transformations Science 2018, 360, 873.
144.	Simon J. Bonyhady, Daniel E. DeRosha, Javier Vela, David J. Vinyard, Ryan E. Cowley, Brandon Q. Mercado, William W. Brennessel, Patrick L. Holland Iron and cobalt diazoalkane complexes supported by β-diketiminate ligands: a synthetic, spectroscopic and computational investigation Inorg. Chem. 2018, 57, 5959–5972.
143.	Daniel E. DeRosha, Patrick L. Holland Incorporating light atoms into synthetic analogues of FeMoco Proc. Natl. Acad. Sci. USA 2018, 115, 5054-5056.
142.	Daniël L. J. Broere, Brandon Q. Mercado, James T. Lukens, Avery C. Vilbert, Gourab Banerjee, Hannah M. C. Lant, Shin Hee Lee, Eckhard Bill, Stephen Sproules, Kyle M. Lancaster, Patrick L. Holland Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes Chem. Eur. J. 2018, 24, 9417-9425.
141.	Daniël L. J. Broere, Brandon Q. Mercado, Patrick L. Holland Selective Conversion of CO₂ to Isocyanate by Low–Coordinate Iron Complexes Angew. Chem. Int. Ed. 2018, 57, 6507-6511.
140.	Daniël L. J. Broere, Brandon Q. Mercado, Eckhard Bill, Kyle M. Lancaster, Stephen Sproules, Patrick L. Holland Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry Inorg. Chem. 2018, 57, 9580-9591.
139.	Daniël L. J. Broere, Patrick L. Holland Boron compounds tackle dinitrogen Science 2018, 359, 871. (reprint)
138.	Elitsour Rozen, Yaron Erlich, Megan E. Reesbeck, Patrick L. Holland, Chaim N. Sukenik Functionalized Self-Assembled Monolayers Bearing Diiminate Complexes Immobilized through Covalently Anchored Ligands Langmuir 2018, 34, 13472-13480.
137.	Gannon P. Connor, Nicholas Lease, Andrea Casuras, Alan S. Goldman, Patrick L. Holland, James M. Mayer Protonation and electrochemical reduction of rhodium- and iridium-dinitrogen complexes in organic solution Dalton Trans. 2017, 46, 14325-14330.
136.	Nicholas A. Arnet, Sean F. McWilliams, Daniel E. DeRosha, Brandon Q. Mercado, Patrick L. Holland Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron Inorg. Chem. 2017, 56, 9185-9193.
135.	Masaki Horitani, Katarzyna Grubel, Sean F. McWilliams, Bryan D. Stubbert, Brandon Q. Mercado, Ying Yu, Prabhuodeyara M. Gurubasavaraj, Nicholas S. Lees, Patrick L. Holland, Brian M. Hoffman ENDOR Characterization of an Iron-Alkene Complex Provides Insight into a Corresponding Organometallic Intermediate of Nitrogenase Chem. Sci. 2017, 8, 5941-5948.
134.	Sean F. McWilliams, Emma Brennan-Wydra, K. Cory MacLeod, Patrick L. Holland Density Functional Calculations for Prediction of ⁵⁷Fe Mössbauer Isomer Shifts and Quadrupole Splittings in β-Diketiminate Complexes ACS Omega 2017, 2, 2594-2606.
133.	Patrick L. Holland Reaction: Opportunities for Sustainable Catalysts Chem 2017, 2, 443-444.
132.	Daniël L. J. Broere, Ilija Čorić, Anna Brosnahan, Patrick L. Holland Quantitation of the THF Content in Fe[N(SiMe₃)₂]₂·xTHF Inorg. Chem. 2017, 56, 3140–3143.
131.	Julian C. Lo, Dongyoung Kim, Chung-Mao Pan, Jacob T. Edwards, Yuki Yabe, Jinghan Gui, Tian Qin, Sara Gutiérrez, Jessica Giacoboni, Myles W. Smith, Patrick L. Holland, Phil S. Baran Fe-Catalyzed C-C Bond Construction from Olefins via Radicals J. Am. Chem. Soc. 2017, 139, 2484-2503.
130.	Daniel E. DeRosha, Brandon Q. Mercado, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Patrick L. Holland Enhancement of C-H Oxidizing Ability in Co-O₂ Complexes through an Isolated Heterobimetallic Oxo Intermediate Angew. Chem. Int. Ed. 2017, 56, 3211–3215.
129.	Megan E. Reesbeck, Katarzyna Grubel, Daniel Kim, William W. Brennessel, Brandon Q. Mercado, Patrick L. Holland Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II) Inorg. Chem. 2017, 56, 1019-1022.
128.	K. Cory MacLeod, Richard A. Lewis, Daniel E. DeRosha, Brandon Q. Mercado, Patrick L. Holland C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron Angew. Chem. Int. Ed. 2017, 56, 1069-1072.
127.	Amy M. Speelman, Patrick L. Holland Sulfur-Supported Iron Complexes for Understanding N₂ Reduction In: Nishibayashi Y. (eds) Nitrogen Fixation. 2017, Topics in Organometallic Chemistry, vol 60. Springer, New York, 197-213.
126.	Gannon P. Connor, Patrick L. Holland Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction Catalysis Today 2017, 286, 21-40.
125.	Sarina M. Bellows, Nicholas A. Arnet, Prabhuodeyara M. Gurubasavaraj, William W. Brennessel, Eckhard Bill, Thomas R. Cundari, Patrick L. Holland The Mechanism of N-N Double Bond Cleavage by an Iron(II)-Hydride Complex J. Am. Chem. Soc. 2016, 138, 12112–12123.
124.	Yuchen Liu, David J. Vinyard, Megan E. Reesbeck, Tateki Suzuki, Kasidet Manakongtreecheep, Patrick L. Holland, Gary W. Brudvig, and Dieter Söll A [3Fe-4S] cluster is required for tRNA thiolation in archaea and eukaryotes Proc. Natl. Acad. Sci. USA 2016, 113, 12703-12708.
123.	K. Cory MacLeod, Fabian S. Menges, Sean F. McWilliams, Stephanie M. Craig, Brandon Q. Mercado, Mark A. Johnson, Patrick L. Holland Alkali-Controlled C-H Cleavage or N-C Bond Formation by N₂-Derived Iron Nitrides and Imides J. Am. Chem. Soc. 2016, 138, 11185-11191.
122.	K. Cory MacLeod, Sean F. McWilliams, Brandon Q. Mercado, Patrick L. Holland Stepwise N-H Bond Formation From N₂-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia Chem. Sci. 2016, 7, 5736-5746.
121.	Ilija Čorić, Patrick L. Holland Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands J. Am. Chem. Soc. 2016, 138, 7200-7211.
120.	Sarina M. Bellows, William W. Brennessel, Patrick L. Holland Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate β-Diketiminate Iron Complexes Eur. J. Inorg. Chem. 2016, , 3344-3355.
119.	Sean F. McWilliams, Kenton R. Rodgers, Gudrun Lukat-Rodgers, Brandon Q. Mercado, Katarzyna Grubel, Patrick L. Holland Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes Inorg. Chem. 2016, 55, 2960-2968.
118.	Chi Chen, Maxwell Hecht, Aydin Kavara, William W. Brennessel, Brandon Q. Mercado, Daniel J. Weix, Patrick L. Holland Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst J. Am. Chem. Soc. 2015, 137, 13244-13247.
117.	Nicholas A. Arnet, Thomas R. Dugan, Fabian S. Menges, Brandon Q. Mercado, William W. Brennessel, Eckhard Bill, Mark A. Johnson, Patrick L. Holland Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride J. Am. Chem. Soc. 2015, 137, 13220-13223. (Highlight in Nature Chemical Biology)
116.	Ilija Čorić, Brandon Q. Mercado, Eckhard Bill, David J. Vinyard, Patrick L. Holland Binding of dinitrogen to an iron–sulfur–carbon site Nature 2015, 526, 96-99.
115.	Malik H. Al-Afyouni, Elizaveta Suturina, Shubhrodeep Pathak, Mihail Atanasov, Eckhard Bill, Daniel E. DeRosha, William W. Brennessel, Frank Neese, Patrick L. Holland Spin Isomers and Ligand Isomerization in a Three-Coordinate Cobalt(I) Carbonyl Complex J. Am. Chem. Soc. 2015, 137, 10689-10699.
114.	Chi Chen, Sarina M. Bellows, Patrick L. Holland Tuning steric and electronic effects in transition-metal β-diketiminate complexes Dalton Trans. 2015, 44, 16654-16670. Open Access
113.	Sean F. McWilliams, Patrick L. Holland Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes Acc. Chem. Res. 2015, 48, 2059–2065.
112.	Megan E. Reesbeck, Meghan M. Rodriguez, William W. Brennessel, Brandon Q. Mercado, David J. Vinyard, Patrick L. Holland Oxidized and Reduced [2Fe-2S] Clusters from an Iron(I) Synthon J. Biol. Inorg. Chem. 2015, 20, 875-883.
111.	Patrick L. Holland Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts Acc. Chem. Res. 2015, 48, 1696-1702.
110.	Simon J. Bonyhady, Jonathan M. Goldberg, Nicole Wedgwood, Thomas R. Dugan, Andrew G. Eklund, William W. Brennessel, Patrick L. Holland Cobalt(II) Complex of a Diazoalkane Radical Anion Inorg. Chem. 2015, 54, 5148-5150.
109.	Amit Das, Zhiji Han, William W. Brennessel, Patrick L. Holland, Richard Eisenberg Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water ACS Catal. 2015, 5, 1397-1406.
108.	Katarzyna Grubel, William W. Brennessel, Brandon Q. Mercado, Patrick L. Holland Alkali Metal Control over N−N Cleavage in Iron Complexes J. Am. Chem. Soc. 2014, 136, 16807-16816.
107.	Timothy E. Machonkin, Monica D. Boshart, Jeremy A. Schofield, Meghan M. Rodriguez, Katarzyna Grubel, Dalia Rokhsana, William W. Brennessel, Patrick L. Holland Structural and Spectroscopic Characterization of Iron(II), Cobalt(II), and Nickel(II) ortho-Dihalophenolate Complexes: Insights into Metal–Halogen Secondary Bonding Inorg. Chem. 2014, 53, 9837-9848.
106.	Richard A. Lewis, K. Cory MacLeod, Brandon Q. Mercado, Patrick L. Holland Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons Chem. Commun. 2014, 50 , 11114-11117.
105.	K. Cory MacLeod, David J. Vinyard, Patrick L. Holland A Multi-iron System Capable of Rapid N₂ Formation and N₂ Cleavage J. Am. Chem. Soc. 2014, 136, 10226-10229.
104.	John A. Gladysz, et al. Organometallics Roundtable 2013-2014 Organometallics 2014, 33, 1505-1527.
103.	Thomas R. Dugan, Eckhard Bill, K. Cory MacLeod, William W. Brennessel, Patrick L. Holland Synthesis, Spectroscopy and Hydrogen/Deuterium Exchange in High-Spin Iron(II) Hydride Complexes Inorg. Chem. 2014, 53, 2370-2380.
102.	Chi Chen, Thomas R. Dugan, William W. Brennessel, Daniel J. Weix, Patrick L. Holland Z-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes J. Am. Chem. Soc. 2014, 136, 945-955. (Coverage in Org. Chem. Highlights)
101.	Karen P. Chiang, Sarina M. Bellows, William W. Brennessel, Patrick L. Holland Multimetallic cooperativity in activation of dinitrogen at iron-potassium sites Chem. Sci. 2014, 5, 267-274.
100.	Wenwen Yao, Prabhuodeyara M. Gurubasavaraj, Patrick L. Holland All-Ferrous Iron-Sulfur Clusters Struct. Bonding 2014, 160, 1-37.
99.	Ryan E. Cowley, Matthew R. Golder, Nathan A. Eckert, Malik H. Al-Afyouni, Patrick L. Holland Mechanism of Catalytic Nitrene Transfer using Iron(I)-Isocyanide Complexes Organometallics 2013, 32, 5289-5298.
98.	Zhiji Han, Luxi Shen, William W. Brennessel, Patrick L. Holland, Richard Eisenberg Nickel Pyridylthiolate Complexes for the Photocatalytic Production of Hydrogen from Aqueous Solutions in Noble-Metal-Free Systems J. Am. Chem. Soc. 2013, 135, 14659-14669.
97.	Sarina M. Bellows, Thomas R. Cundari, Patrick L. Holland Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)- and Cobalt(II)-Alkyl Complexes Organometallics 2013, 32, 4741-4751. (Part of Virtual Issue Honoring Robert Bergman’s 2017 Wolf Prize in Chemistry)
96.	Christopher J. Pollock, Katarzyna Grubel, Patrick L. Holland, Serena DeBeer Experimentally Quantifying Small Molecule Bond Activation Using Valence-to-Core X-ray Emission Spectroscopy J. Am. Chem. Soc. 2013, 135, 11803-11808.
95.	Zuofeng Chen, Christopher R. K. Glasson, Patrick L. Holland, Thomas J. Meyer Electrogenerated polypyridyl ruthenium hydride and ligand activation for water reduction to hydrogen and acetone to iso-propanol Phys. Chem. Chem. Phys. 2013, 15, 9503-9507.
94.	Roman M. Davydov, Matthew P. McLaughlin, Eckhard Bill, Brian M. Hoffman, Patrick L. Holland Generation of High-Spin Iron(I) in a Protein Environment Using Cryoreduction Inorg. Chem. 2013, 52, 7323-7325.
93.	Thomas R. Dugan, K. Cory MacLeod, William W. Brennessel, Patrick L. Holland Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges Eur. J. Inorg. Chem. 2013, , 3891-3897.
92.	Bryan D. Stubbert, Javier Vela, William W. Brennessel, Patrick L. Holland A Sulfide-Bridged Diiron(II) Complex with a cis-N₂H₄ Ligand Z. Anorg. Allg. Chem. 2013, 639, 1351-1355.
91.	P. Chandrasekaran, Karen P. Chiang, Dennis Nordlund, Uwe Bergmann, Patrick L. Holland, Serena DeBeer On the Sensitivity of X-ray Core Spectroscopy to Changes in Metal Ligation: A Systematic Study of Low-Coordinate High-Spin Ferrous Complexes Inorg. Chem. 2013, 52, 6286-6298.
90.	K. Cory MacLeod, Patrick L. Holland Recent Developments in Homogeneous Dinitrogen Reduction by Molybdenum and Iron Nature Chem. 2013, 5, 559-565.
89.	Thomas R. Dugan, Eckhard Bill, K. Cory MacLeod, Gemma J. Christian, Ryan E. Cowley, William W. Brennessel, Shengfa Ye, Frank Neese, Patrick L. Holland Reversible C-C Bond Formation Between Redox-Active Pyridine Ligands in Iron Complexes J. Am. Chem. Soc. 2012, 134, 20352-20364.
88.	Matthew P. McLaughlin, Marius Retegan, Eckhard Bill, Thomas M. Payne, Hannah S. Shafaat, Salvador Peña, Jawahar Sudhamsu, Amy E. Ensign, Brian R. Crane, Frank Neese, Patrick L. Holland Azurin as a protein scaffold for a low-coordinate non-heme iron site with a small-molecule binding pocket J. Am. Chem. Soc. 2012, 134, 19746-19757.
87.	Brian L. Edelbach, Blaze M. Pharoah, Sarina M. Bellows, Peter R. Thayer, Charles N. Fennie, Ryan E. Cowley, Patrick L. Holland An Expedient Synthesis of 2,4,6-Tris(trifluoromethyl)aniline Synthesis 2012, 44, 3595-3597.
86.	Zhiji Han, Fen Qiu, Richard Eisenberg, Patrick L. Holland, Todd D. Krauss Robust Photogeneration of H₂ in Water Using Semiconductor Nanocrystals and a Nickel Catalyst Science 2012, 338, 1321 1324.
85.	Christopher R. K. Glasson, Wenjing Song, Dennis L. Ashford, Aaron Vannucci, Zuofeng Chen, Javier J. Concepcion, Patrick L. Holland, Thomas J. Meyer Self-Assembled Bilayers on Indium-Tin Oxide (SAB-ITO) Electrodes: A Design for Chromophore-Catalyst Photoanodes Inorg. Chem. 2012, 51, 8637-8639.
84.	Meghan M. Rodriguez, Bryan D. Stubbert, Christopher C. Scarborough, William W. Brennessel, Eckhard Bill, Patrick L. Holland Isolation and Characterization of Stable Iron(I)-Sulfide Complexes Angew. Chem. Int. Ed. 2012, 51, 8246-8520.
83.	Ryan E. Cowley, Patrick L. Holland Ligand Effects on Hydrogen Atom Transfer from Hydrocarbons to Three-Coordinate Iron Imides Inorg. Chem. 2012, 51, 8352-8361.
82.	Travis M. Figg, Patrick L. Holland, Thomas R. Cundari Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation Inorg. Chem. 2012, 51, 7546-7550.
81.	William R. McNamara, Zhiji Han, Chih-Juo Yin, William W. Brennessel, Patrick L. Holland, Richard Eisenberg Cobalt-Dithiolene Complexes for the Photocatalytic and Electrocatalytic Reduction of Protons in Aqueous Solutions Proc. Natl. Acad. Sci. USA 2012, 109, 15594-15599.
80.	Karen P. Chiang, Christopher C. Scarborough, Masaki Horitani, Nicholas S. Lees, Keying Ding, Thomas R. Dugan, William W. Brennessel, Eckhard Bill, Brian M. Hoffman, Patrick L. Holland Characterization of the Fe-H Bond in a Three-Coordinate Terminal Hydride Complex of Iron(I) Angew. Chem. Int. Ed. 2012, 51, 3658-3662.
79.	Katarzyna Grubel, Patrick L. Holland New Iron-Sulfur Clusters Help Hydrogenases Tolerate Oxygen Angew. Chem. Int. Ed. 2012, 51, 3308-3310.
78.	Thomas R. Dugan, Jonathan M. Goldberg, William W. Brennessel, Patrick L. Holland Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C-F Activation Reactions Organometallics 2012, 31, 1349-1360.
77.	Zhiji Han, William R. McNamara, Min-Sik Eum, Patrick L. Holland, Richard Eisenberg A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System Angew. Chem. Int. Ed. 2012, 51, 1667-1670.
76.	Ryan E. Cowley, Gemma J. Christian, William W. Brennessel, Frank Neese, Patrick L. Holland A Reduced β-Diketiminatoiron Complex with End-on and Side-on Nitriles: Strong Backbonding or Ligand Non-Innocence? Eur. J. Inorg. Chem. 2012, , 479-483.
75.	Barbara A. Reisner, Joanne L. Stewart, B. Scott Williams, Laurel A. Goj, Patrick L. Holland, Hilary J. Eppley, and Adam R. Johnson Virtual Inorganic Pedagogical Electronic Resource Learning Objects in Organometallic Chemistry J. Chem. Educ. 2012, 89, 185-187.
74.	Meghan M. Rodriguez, Eckhard Bill, William W. Brennessel, Patrick L. Holland N₂ Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex Science 2011, 334, 780-783.
73.	Matthew P. McLaughlin, Thomas H. Darrah, Patrick L. Holland Palladium(II) and platinum(II) bind strongly to an engineered blue copper protein Inorg. Chem. 2011, 50, 11294-11296.
72.	Mario U. Delgado-Jaime, Benjamin R. Dible, Karen P. Chiang, William W. Brennessel, Patrick L. Holland, Uwe Bergmann, Serena DeBeer Identification of Light Atoms within Multinuclear Metal Clusters using Valence-to-Core X-Ray Emission Spectroscopy Inorg. Chem. 2011, 50, 10709-10717.
71.	Theresa M. McCormick, Zhiji Han, David J. Weinberg, Patrick L. Holland, Richard Eisenberg The Impact of Ligand Exchange in Hydrogen Production from Cobaloxime-Containing Photocatalytic Systems Inorg. Chem. 2011, 50, 10660-10666.
70.	William R. McNamara, Zhiji Han, Paul J. Alperin, William W. Brennessel, Patrick L. Holland, Richard Eisenberg Cobalt-Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons J. Am. Chem. Soc. 2011, 133, 5123-5132.
69.	Benjamin R. Dible, Ryan E. Cowley, Patrick L. Holland Remote Substitution on N-Heterocyclic Carbenes Heightens the Catalytic Reactivity of Their Palladium Complexes Organometallics 2011, 30, 5123-5132.
68.	Thomas R. Dugan, Xianru Sun, Elena V. Rybak-Akimova, Olayinka Olatunji-Ojo, Thomas R. Cundari, Patrick L. Holland A Masked Two-Coordinate Cobalt(I) Complex That Activates C-F Bonds J. Am. Chem. Soc. 2011, 133, 12418-12421.
67.	Patrick L. Holland Techniques Used in Functional and Structural Modeling of Nitrogenase Methods in Molecular Biology - Nitrogen Fixation 2011, (M. Ribbe, ed.), Springer: New York, 249-263.
66.	Matthew P. McLaughlin, Theresa M. McCormick, Richard Eisenberg, Patrick L. Holland A stable molecular nickel catalyst for the homogeneous photogeneration of hydrogen in aqueous solution Chem. Commun. 2011, 47, 7989-7981.
65.	Ryan E. Cowley, Nathan A. Eckert, Sridhar Vaddadi, Travis M. Figg, Thomas R. Cundari, Patrick L. Holland Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex J. Am. Chem. Soc. 2011, 133, 9796-9811.
64.	Patrick L. Holland All square with high-spin iron(II) Nature Chem. 2011, 3, 507-508.
63.	Patrick L. Holland Two-Coordinate Transition Metal Centers With Metal-Metal Bonds Angew. Chem. Int. Ed. 2011, 50, 6213-6214.
62.	Ryan E. Cowley, Patrick L. Holland C-H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product Inorg. Chim. Acta 2011, 369, 40-44.
61.	Sara S. Rocks, William W. Brennessel, Timothy E. Machonkin, Patrick L. Holland Solution and Structural Characterization of Iron(II) Complexes with Ortho-Halogenated Phenolates: Insights into Potential Substrate Binding Modes in Hydroquinone Dioxygenases Inorg. Chem. 2010, 49, 10914-10929.
60.	Ryan E. Cowley, Nathan J. DeYonker, Nathan A. Eckert, Thomas R. Cundari, Serena DeBeer, Eckhard Bill, Xavier Ottenwaelder, Christine Flaschenriem, Patrick L. Holland Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation Inorg. Chem. 2010, 49, 6172-6187.
59.	Daniel J. Mindiola, Patrick L. Holland, Timothy H. Warren Complexes of Bulky Beta-Diketiminate Ligands: Introduction Inorg. Synth. 2010, 35, 1-4.
58.	Matthew S. Varonka, Timothy H. Warren, Thomas R. Dugan, Ryan E. Cowley, Patrick L. Holland Beta-Diketiminate Precursors HL^Me,Me3 and TlL^Me,Me3 Inorg. Synth. 2010, 35, 4-8.
57.	Debashis Adhikari, Ba L. Tran, Francisco J. Zuno-Cruz, Gloria Sanchez Cabrera, Daniel J. Mindiola, Karen P. Chiang, Ryan E. Cowley, Thomas R. Dugan, Patrick L. Holland Beta-Diketiminate Precursors L^Me,iPr2H, [L^Me,iPr2Li]_x, and [L^tBu,iPr2K]_x Inorg. Synth. 2010, 35, 8-13.
56.	Ryan E. Cowley, Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Francisco J. Zuno-Cruz, Gloria Sanchez Cabrera, Daniel J. Mindiola Beta-Diketiminate Precursors L^tBu^,^iPr2H and L^tBu^,^iPr2Li(THF) Inorg. Synth. 2010, 35, 13-19.
55.	Bryan D. Stubbert, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola Iron 2,4-Bis-(2,6-diisopropylphenylimido)pentyl Chloride Dimer Inorg. Synth. 2010, 35, 38-41.
54.	Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola Iron 2,2,6-6-Tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl Chloride Inorg. Synth. 2010, 35, 41-43.
53.	Keying Ding, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola Cobalt 2,2,6-6-Tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl Chloride Inorg. Synth. 2010, 35, 43-45.
52.	Marie M. Melzer, Elzbieta Kogut, Matthew S. Varonka, Stefan Wiese, Timothy H. Warren, Sara S. Rocks, Patrick L. Holland Beta-Diketiminate Supported Nickel(II) and Nickel(I) Complexes of L^Me,Me3 Inorg. Synth. 2010, 35, 45-48.
51.	Thomas R. Dugan, Patrick L. Holland, Stefan Wiese, Timothy H. Warren Nickel 2,4-Bis-(2,6-diisopropylphenylimido)pentyl Chloride Dimer Inorg. Synth. 2010, 35, 48-50.
50.	Yosra M. Badiei, Timothy H. Warren, Karen P. Chiang, Patrick L. Holland Bis[Copper 2,4-Bis-(2,4,6-trimethylphenylimido)pentyl] Toluene Inorg. Synth. 2010, 35, 50-53.
49.	Patrick L. Holland, Marie M. Melzer, Timothy H. Warren Copper 2,4-Bis-(2,6-diisopropylphenylimido)pentyl Chloride Inorg. Synth. 2010, 35, 54-55.
48.	Patrick L. Holland Metal-Dioxygen and Metal-Dinitrogen Complexes: Where Are The Electrons? Dalton Trans. 2010, 39, 5415-5425.
47.	Timothy E. Machonkin, Patrick L. Holland, Kristine N. Smith, Justin S. Liberman, Adriana Dinescu, Thomas R. Cundari, Sara S. Rocks Determination of the Active Site of Sphingomonas chlorophenolica 2,6-dichloro-p-hydroquinone dioxygenase (PcpA) J. Biol. Inorg. Chem. 2010, 15, 291-301.
46.	Keying Ding, Thomas R. Dugan, William W. Brennessel, Eckhard Bill, and Patrick L. Holland Synthesis, Properties, and Reactivity of Diketiminate-Supported Cobalt Fluoride Complexes Organometallics 2009, 28, 6650-6656.
45.	Keying Ding, Ferdous Zannat, James C. Morris, William W. Brennessel, and Patrick L. Holland Coordination of N-Methylpyrrolidone to Iron(II) J. Organomet. Chem. 2009, 694, 4204-4208.
44.	Keying Ding, William W. Brennessel, and Patrick L. Holland Three-Coordinate and Four-Coordinate Cobalt Hydride Complexes That React with Dinitrogen J. Am. Chem. Soc. 2009, 131, 10804-10805. Correction
43.	Keying Ding, Aaron W. Pierpont, William W. Brennessel, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Thomas R. Cundari, Eckhard Bill and Patrick L. Holland Cobalt-Dinitrogen Complexes with Weakened N-N Bonds J. Am. Chem. Soc. 2009, 131, 9471-9472.
42.	Thomas R. Dugan, Patrick L. Holland New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H₂ J. Organomet. Chem. 2009, 694, 2825-2830.
41.	Karen P. Chiang, Pamela M. Barrett, Feizhi Ding, Jeremy M. Smith, Savariraj Kingsley, William W. Brennessel, Meghan M. Clark, Rene J. Lachicotte, Patrick L. Holland Ligand Dependence of Binding to Three-Coordinate Fe(II) Complexes Inorg. Chem. 2009, 48, 5106-5116.
40.	Ryan E. Cowley, Eckhard Bill, Frank Neese, William W. Brennessel, Patrick L. Holland Iron(II) Complexes With Redox-Active Tetrazene (RNNNNR) Ligands Inorg. Chem. 2009, 48, 4828-4836.
39.	Azwana R. Sadique, William W. Brennessel, Patrick L. Holland A diketiminate-bound diiron complex with a bridging carbonate ligand Acta Cryst. C 2009, 65, m174-m176.
38.	Meghan M. Clark, William W. Brennessel, Patrick L. Holland Bis(η⁵-pentamethylcyclopentadienyl)cobalt(II) Acta Cryst. C 2009, 65, m391. More on Decamethylcobaltocene
37.	Ryan E. Cowley, Nathan A. Eckert, Jerome E. Elhaïk, Patrick L. Holland Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates Chem. Commun. 2009, , 1760-1762.
36.	Patrick L. Holland Nitrogen Fixation McGraw-Hill Yearbook of Science & Technology 2009, , 255-256.
35.	Sara S. Rocks, William W. Brennessel, Timothy E. Machonkin, Patrick L. Holland Solid-State and Proton NMR Characterization of an Iron(II) Complex of a Tridentate, Facially Coordinating N,N,O Donor Ligand Inorg. Chim. Acta 2009, 362, 1387-1390.
34.	Sebastian Stoian, Jeremy M. Smith, Patrick L. Holland, Eckard Münck, Emile L. Bominaar Mössbauer, EPR, and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complex Inorg. Chem. 2008, 47, 8687-8695.
33.	Patrick L. Holland Electronic Structure and Reactivity of Three-Coordinate Iron Complexes Acc. Chem. Res. 2008, 41, 905-914.
32.	Ying Yu, Azwana R. Sadique, Jeremy M. Smith, Thomas R. Dugan, Ryan E. Cowley, William W. Brennessel, Christine J. Flaschenriem, Eckhard Bill, Thomas R. Cundari, Patrick L. Holland The Reactivity Patterns of Low-Coordinate Iron Hydride Complexes J. Am. Chem. Soc. 2008, 130, 6624-6638.
31.	Ryan E. Cowley, Jerome Elhaik, Nathan A. Eckert, William W. Brennessel, Eckhard Bill, Patrick L. Holland A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides J. Am. Chem. Soc. 2008, 130, 6074-6075. Highlight in Chemical & Engineering News
30.	Azwana R. Sadique, William W. Brennessel, and Patrick L. Holland Reduction of CO₂to CO Using Low-Coordinate Iron: Formation of a Four-Coordinate Iron Dicarbonyl Complex and a Bridging Carbonate Complex Inorg. Chem. 2008, 47, 784-786.
29.	Nicholas S. Lees, Rebecca L. McNaughton, Wilda Vargas Gregory, Patrick L. Holland, and Brian M. Hoffman ENDOR Characterization of a Synthetic Diiron Hydrazido Complex as a Model for Nitrogenase Intermediates J. Am. Chem. Soc. 2008, 130, 546-555.
28.	Azwana R. Sadique, Elizabeth A. Gregory, William W. Brennessel, and Patrick L. Holland Mechanistic Insight into N=N Cleavage by a Low-Coordinate Iron(II) Hydride Complex J. Am. Chem. Soc. 2007, 129, 8112-8121. Editor's Choice in Science
27.	Javier Vela, Liwei Zhu, Christine J. Flaschenriem, William W. Brennessel, Rene J. Lachicotte, and Patrick L. Holland Macrocyclic Binucleating β-Diketiminate Ligands and their Lithium, Aluminum, and Zinc Complexes Organometallics 2007, 26, 3416-3423.
26.	Ying Yu, William W. Brennessel, and Patrick L. Holland Borane B-C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N-N Bond Cleavage by the Hydridoborate Product Organometallics 2007, 26, 3217-3226.
25.	Javier Vela, Jordi Cirera, Jeremy M. Smith, Rene J. Lachicotte, Christine J. Flaschenriem, Santiago Alvarez, and Patrick L. Holland Quantitative Geometric Descriptions of the Belt Iron Atoms of the Iron-Molybdenum Cofactor of Nitrogenase and Synthetic Iron(II) Model Complexes Inorg. Chem. 2007, 46, 60-71.
24.	Nathan A. Eckert, Sridhar Vaddadi, Sebastian Stoian, Rene J. Lachicotte, Thomas R. Cundari, and Patrick L. Holland Coordination Number Dependence of Reactivity in an Imidoiron(III) Complex Angew. Chem., Int. Ed. Engl. 2006, 45, 6868-6871.
23.	Travis J. Hebden, William W. Brennessel, Christine J. Flaschenriem, and Patrick L. Holland A dinucleating ligand related to the β-diketiminates Dalton Trans. 2006, , 3855-3857.
22.	Sebastian A. Stoian, Javier Vela, Jeremy M. Smith, Azwana R. Sadique, Patrick L. Holland, Eckard Münck, and Emile L. Bominaar Mössbauer and Computational Study of an N₂-Bridged Diiron Diketiminate Complex: Parallel Alignment of the Iron Spins by Direct Antiferromagnetic Exchange with Activated Dinitrogen J. Am. Chem. Soc. 2006, 128, 10181-10192.
21.	Ying Yu, Jeremy M. Smith, Christine J. Flaschenriem, and Patrick L. Holland Binding Affinity of Alkynes and Alkenes to Low-Coordinate Iron Inorg. Chem. 2006, 45, 5742-5751. cover of Inorg. Chem.
20.	Javier Vela, Sridhar Vaddadi, Savariraj Kingsley, Christine J. Flaschenriem, Rene J. Lachicotte, Thomas R. Cundari, Patrick L. Holland Bidentate Coordination of Pyrazolate in Low-Coordinate Iron(II) and Nickel(II) Complexes Angew. Chem., Int. Ed. Engl. 2006, 45, 1607-1611.
19.	Jeremy M. Smith, Azwana R. Sadique, Thomas R. Cundari, Kenton R. Rodgers, Gudrun Lukat-Rodgers, Rene J. Lachicotte, Christine J. Flaschenriem, Javier Vela, and Patrick L. Holland Studies of Low-Coordinate Iron Dinitrogen Complexes J. Am. Chem. Soc. 2006, 128, 756-769.
18.	Nathan A. Eckert, Adriana Dinescu, Thomas R. Cundari, Patrick L. Holland A T-Shaped Three-Coordinate Nickel(I) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d⁹ Complexes Inorg. Chem. 2005, 44, 7702-7704.
17.	Nathan A. Eckert, Sebastian Stoian, Jeremy M. Smith, Emile L. Bominaar, Eckard Münck, Patrick L. Holland Synthesis, Structure, and Spectroscopy of an Oxodiiron(II) Complex J. Am. Chem. Soc. 2005, 127, 9344-9345.
16.	Sebastian Stoian, Ying Yu, Jeremy M. Smith, Patrick L. Holland, Emile L. Bominaar, Eckard Münck Mössbauer, EPR and Crystallographic Characterization of a High-Spin Fe(I) Diketiminate Complex with Orbital Degeneracy Inorg. Chem. 2005, 44, 4915-4922.
15.	Javier Vela, Jeremy M. Smith, Ying Yu, Nicole A. Ketterer, Christine J. Flaschenriem, Rene J. Lachicotte, Patrick L. Holland Synthesis and Reactivity of Low-Coordinate Iron(II) Fluoride Complexes and Their Use in the Catalytic Hydrodefluorination of Fluorocarbons J. Am. Chem. Soc. 2005, 127, 7857-7870.
14.	Elizabeth A. Gregory, Rene J. Lachicotte, Patrick L. Holland A Cationic Three-Coordinate Iron(II) Complex and the Reaction of Diketiminate with Ethyl Diazoacetate Organometallics 2005, 24, 1803-1805.
13.	Patrick L. Holland Low-Coordinate Iron Complexes as Synthetic Models of Nitrogenase Can. J. Chem. 2005, 83, 296-301.
12.	Javier Vela, Sridhar Vaddadi, Thomas R. Cundari, Jeremy M. Smith, Elizabeth A. Gregory, Rene J. Lachicotte, Christine J. Flaschenriem, Patrick L. Holland Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies Organometallics 2004, 23, 5226-5239. Correction
11.	Nathan A. Eckert, Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland Low-coordinate Fe(II) Amido Complexes of β-Diketiminates: Synthesis, Structure and Reactivity Inorg. Chem. 2004, 43, 3306-3321.
10.	Javier Vela, Sebastian Stoian, Christine Flaschenriem, Eckard Münck, Patrick L. Holland A Sulfido-Bridged Diiron(II) Compound and Its Reactions with Nitrogenase-Relevant Substrates J. Am. Chem. Soc. 2004, 126, 4522-4523. Correction
9.	Patrick L. Holland “Nitrogen Fixation,” In Comprehensive Coordination Chemistry 2 (McCleverty, J., Meyer, T. J., Eds.) 2004, Vol. 8; Elsevier: Oxford, 569-599. On-line access
8.	Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland N=N Bond Cleavage by a Low-Coordinate Iron(II) Hydride Complex J. Am. Chem. Soc. 2003, 125, 15752-15753.
7.	Nathan A. Eckert, Emily M. Bones, Rene J. Lachicotte, Patrick L. Holland Nickel Complexes of a Bulky β-Diketiminate Ligand Inorg. Chem. 2003, 42, 1720-1725.
6.	Javier Vela, Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland Alkyl group isomerisation in three-coordinate iron(II) complexes Chem. Commun. 2002, , 2886-2887.
5.	Patrick L. Holland, Thomas R. Cundari, Lanyn L. Perez, Nathan A. Eckert, Rene J. Lachicotte Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel J. Am. Chem. Soc. 2002, 124, 14416-14424.
4.	Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland Three-coordinate, 12-electron organometallic complexes of iron(II): synthesis and insertion of CO to give square pyramidal complexes Organometallics 2002, 21, 4808-4814.
3.	Hanspeter Andres, Emile M. Bominaar, Jeremy M. Smith, Nathan A. Eckert, Patrick L. Holland, Eckard Münck Planar Three-Coordinate High-Spin Fe(II) Complexes with Large Orbital Angular Momentum: Mössbauer, Electron Paramagnetic Resonance, and Electronic Structure Studies J. Am. Chem. Soc. 2002, 124, 3012-3025. Correction
2.	Jeremy M. Smith, Rene J. Lachicotte, Karl A. Pittard, Thomas R. Cundari, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Patrick L. Holland Stepwise Reduction of N-N Bond Order by a Low-Coordinate Iron Complex J. Am. Chem. Soc. 2001, 123, 9222-9223.
1.	Jeremy M. Smith, Rene J. Lachicotte, Patrick L. Holland Tuning Metal Coordination Number by Ancillary Ligand Steric Effects: Synthesis of a Three-Coordinate Iron(II) Complex Chem. Commun. 2001, , 1542-1543.